Thursday, February 21, 2008

Isomers

Isomers

Isomers are molecules with the same molecular formula, but different arrangements of atoms. There are different types of isomers, shown by the diagram on the right.

Find out about geometrical isomerism

Functional Isomerism

Functional isomerism, an example of structural isomerism, occurs substances have the same molecular formula but different functional groups. This means that functional isomers belong to different homologous series.
ethanol
methoxymethane
C2H6O
ethanol
methoxymethane
Alcohols have the hydroxyl group,
?OH. Ethers have the functional group R?O?R'.
propanal
propanone (acetone)
C3H6O
propanal
propanone
Aldehydes and ketones both have the carbonyl group C=O. In ketones this is attached to two carbon atoms; in aldehydes it is attached to 1 or 2 hydrogen atoms.

Positional Isomerism

Positional isomerism, an example of structural isomerism, occurs when functional groups are in different positions on the same carbon chain.
butan-1-ol
butan-2-ol
butan-1-ol
butan-2-ol
but-1-ene
but-2-ene
Note: this is cis-but-2-ene, which has a geometric isomer called trans-but-2-ene (select here to find out more)
but-1-ene
but-2-ene
2-methylphenol
3-methylphenol
4-methylphenol
2-methylphenol
3-methylphenol
4-methylphenol

Chain Isomerism

Chain isomerism occurs when the way carbon atoms are linked together is different from compound to compound. It is an example of structural isomerism, and is also called nuclear isomerism.


pentane

pentane
2-methylbutane
2-methylbutane
2,2-dimethylpropane

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